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Last reviewed September 2026

IPCC Industrial-Process (IPPU) Emission Factors — Complete Reference

IPCC industrial process and product use emission factors dataset: 224 factors covering cement and lime calcination, glass and ceramics, ammonia, nitric and adipic acid, petrochemicals, iron and steel, ferroalloys, aluminium smelting and fluorinated gases — reported per gas across CO2, N2O, CH4, CF4, C2F6, C3F8, HFC-23 and SF6 from IPCC 2006 Volume 3 and the 2019 Refinement, flowing through the GreenCalculus MasterBrain and REST API/CSV to your Scope 1 process total.
MasterBrain v2026.284 · updated 6 Nov 2026
SourceIPCC 2006 Vol.3 + 2019 Refinement
SectorIPPU (industrial processes)
Parameters224 rows · 8 gases
GC ImplementationMasterBrain v2026.105
BasisPer gas — not CO₂e

Some emissions come out of a chemical reaction rather than out of a flue. When limestone is calcined to make cement, the CO₂ released is a product of the chemistry itself — it would happen even if the kiln ran on renewable electricity. The IPCC calls this sector IPPU, industrial processes and product use, and it is where a heavy-industry inventory is usually won or lost.

This page publishes the complete IPPU factor set held in MasterBrain: 224 parameters drawn from IPCC 2006 Guidelines Volume 3 and the 2019 Refinement, spanning the mineral, chemical and metal industries plus non-energy products and the carbonate stoichiometry underlying them all.

These factors are per gas, not CO₂e

Unlike a DEFRA-style conversion factor, nothing here is pre-converted to carbon dioxide equivalent. Eight gases appear — CO₂, N₂O, CH₄, CF₄, C₂F₆, C₃F₈, HFC-23 and SF₆ — and each factor stays in the units of the gas it describes. You apply the global warming potential your reporting framework requires. This matters enormously for the non-CO₂ categories: a nitric acid plant emitting 450 tonnes of N₂O is emitting about 273 [GreenCalculus gwp.N2O.ar6_100 · IPCC AR6 WGI Ch 7 Table 7.SM.7 (2021) — AR6 GWP-100 · v2026.284] × that mass in CO₂e terms. Treating a raw N₂O or PFC figure as though it were already CO₂e understates those categories by two orders of magnitude.

What counts as a process emission

A process emission arises from the chemical or physical transformation of a material, not from burning a fuel to supply heat. The distinction is not academic: the two are counted separately, use different factors, and respond to completely different mitigation measures.

Cement is the clearest case. A cement kiln emits CO₂ twice over. It burns fuel to reach 1,450 °C, and that combustion is ordinary stationary combustion. It also drives limestone to decompose — CaCO₃ becomes CaO plus CO₂ — and that release is inherent to making clinker at all. Decarbonising the kiln fuel eliminates the first and leaves the second untouched, which is why the calcination term is the hard part of cement decarbonisation and why it needs its own factor.

The same pattern recurs across the sector: ammonia and hydrogen release CO₂ from the feedstock rather than the fuel; nitric and adipic acid release N₂O from the reaction chemistry; aluminium smelting releases perfluorocarbons during anode effects; and lubricants and paraffin wax oxidise in use rather than being burned as fuel at all.

Where IPPU sits in your inventory

Process emissions from equipment you own or control are Scope 1, exactly like combustion. But they are a distinct category within Scope 1, and both the GHG Protocol and every national inventory expect them reported separately from stationary and mobile combustion.

Process versus combustion emissions at the same facility
Process (IPPU) Combustion
Cause Chemical or physical transformation of the material Oxidation of a fuel to supply energy
Driver Tonnes of product or feedstock Energy or fuel consumed
Scope Scope 1, reported as a separate category Scope 1, stationary or mobile combustion
Factor basis Per gas — this page CO₂e or per gas — IPCC fuel combustion factors
Fuel switching No effect — the chemistry is unchanged Directly reduces the emission

A facility that reports only fuel combustion is not reporting a partial figure — for cement, lime and ammonia it is omitting the majority of the emission.

Two IPCC editions in one table

This dataset draws on both current IPCC sources, and the split is clean rather than overlapping.

Source editions
Edition Rows Covers
IPCC 2006 Guidelines, Vol.3 170 The mineral, chemical and metal industries, non-energy products from fuels, and carbonate stoichiometry
IPCC 2019 Refinement 54 Categories the Refinement added or revised — aluminium PFCs, hydrogen production, rare earths, plus updated nitric-acid and fluorochemical factors

Where the Refinement supersedes a 2006 value, both are published rather than silently merged: national inventories still report on the edition their submission requires, and a value cannot be traced if the edition it came from has been erased. The source_id field in the API response distinguishes them on every row.

The factor tables

All 224 parameters, grouped by IPPU domain. Each row carries its own gas and its own unit — units are process-specific here rather than uniform, so read the unit column on every row.

Mineral industry — 30 rows

Cement, lime, glass and ceramics — CO₂ released when carbonates are calcined.

Mineral industry — IPCC industrial-process emission factors
Category Process / parameter Gas Value Unit
Carbonate other Other process uses of carbonates — Tier 1 default limestone/dolomite blend CO₂ 0.44535 tonne CO₂ per tonne carbonate (85/15 blend)
Cement Cement clinker fraction — Masonry cement default — 0.64 tonne clinker per tonne cement
Cement Cement clinker fraction — Portland cement default — 0.95 tonne clinker per tonne cement
Cement Cement clinker — base emission factor (uncorrected for CKD) CO₂ 0.51 tonne CO₂ per tonne clinker
Cement Cement clinker — default CaO content fraction — 0.65 tonne CaO per tonne clinker
Cement Cement clinker — MgO carbonate-source correction (per 1% MgO) CO₂ 0.011 tonne CO₂ per tonne clinker per 1% MgO from carbonate
Cement Cement clinker — Tier 1 default emission factor (CKD-corrected) CO₂ 0.52 tonne CO₂ per tonne clinker
Cement Cement kiln dust (CKD) — default correction factor CO₂ 1.02 dimensionless multiplier
Ceramics Ceramics — default carbonate content of clay CO₂ 0.1 tonne carbonate per tonne clay
Ceramics Ceramics — default clay-loss multiplier (Tier 1) CO₂ 1.1 dimensionless multiplier
Glass Glass production — Container (Amber/Green) (Tier 2) CO₂ 0.21 tonne CO₂ per tonne glass melted
Glass Glass production — Container (Flint) (Tier 2) CO₂ 0.21 tonne CO₂ per tonne glass melted
Glass Glass production — Fiberglass (E-glass) (Tier 2) CO₂ 0.19 tonne CO₂ per tonne glass melted
Glass Glass production — Fiberglass (Insulation) (Tier 2) CO₂ 0.25 tonne CO₂ per tonne glass melted
Glass Glass production — Float glass (Tier 2) CO₂ 0.21 tonne CO₂ per tonne glass melted
Glass Glass production — Specialty (Lab/Pharma) (Tier 2) CO₂ 0.03 tonne CO₂ per tonne glass melted
Glass Glass production — Specialty (Lighting) (Tier 2) CO₂ 0.2 tonne CO₂ per tonne glass melted
Glass Glass production — Specialty (Tableware) (Tier 2) CO₂ 0.1 tonne CO₂ per tonne glass melted
Glass Glass production — Specialty (TV Funnel) (Tier 2) CO₂ 0.13 tonne CO₂ per tonne glass melted
Glass Glass production — Specialty (TV Panel) (Tier 2) CO₂ 0.18 tonne CO₂ per tonne glass melted
Glass Glass production — Tier 1 default cullet ratio CO₂ 0.5 fraction (cullet mass / total furnace charge)
Glass Glass production — Tier 1 default emission factor CO₂ 0.2 tonne CO₂ per tonne glass
Lime Lime production — Dolomitic lime (developed-country technology) CO₂ 0.86 tonne CO₂ per tonne lime
Lime Lime production — Dolomitic lime (developing-country technology) CO₂ 0.77 tonne CO₂ per tonne lime
Lime Lime production — High-calcium lime (Tier 1) CO₂ 0.75 tonne CO₂ per tonne lime
Lime Lime production — hydrated lime correction factor (default) CO₂ 0.97 dimensionless multiplier
Lime Lime production — Hydraulic lime (Tier 1) CO₂ 0.59 tonne CO₂ per tonne lime
Lime Lime production — Tier 1 composite default (85% high-calcium + 15% dolomitic) CO₂ 0.75 tonne CO₂ per tonne lime
Lime Lime — stoichiometric ratio CO2 per CaO CO₂ 0.785 tonne CO₂ per tonne CaO
Lime Lime — stoichiometric ratio CO2 per CaO·MgO CO₂ 0.913 tonne CO₂ per tonne CaO·MgO

Carbonate stoichiometry — 6 rows

Theoretical CO₂ yield per tonne of pure carbonate, used when a process-specific factor is unavailable.

Carbonate stoichiometry — IPCC industrial-process emission factors
Category Process / parameter Gas Value Unit
Calcite Calcite / aragonite (CaCO3) — stoichiometric CO2 per carbonate CO₂ 0.43971 tonne CO₂ per tonne carbonate
Dolomite Dolomite (CaMg(CO3)2) — stoichiometric CO2 per carbonate CO₂ 0.47732 tonne CO₂ per tonne carbonate
Magnesite Magnesite (MgCO3) — stoichiometric CO2 per carbonate CO₂ 0.52197 tonne CO₂ per tonne carbonate
Rhodochrosite Rhodochrosite (MnCO3) — stoichiometric CO2 per carbonate CO₂ 0.38286 tonne CO₂ per tonne carbonate
Siderite Siderite (FeCO3) — stoichiometric CO2 per carbonate CO₂ 0.37987 tonne CO₂ per tonne carbonate
Sodium carbonate Sodium carbonate / soda ash (Na2CO3) — stoichiometric CO2 per carbonate CO₂ 0.41492 tonne CO₂ per tonne carbonate

Chemical industry — 80 rows

Ammonia, nitric and adipic acid, petrochemicals and carbide production.

Chemical industry — IPCC industrial-process emission factors
Category Process / parameter Gas Value Unit
Acrylonitrile Acrylonitrile — CH4 (Tier 1 default) CH₂ 0.18 kg CH₂ per tonne acrylonitrile
Acrylonitrile Acrylonitrile — CO2, acetonitrile + HCN recovered as product CO₂ 0.79 tonne CO₂ per tonne acrylonitrile
Acrylonitrile Acrylonitrile — CO2, acetonitrile burned for energy recovery/flared CO₂ 0.83 tonne CO₂ per tonne acrylonitrile
Acrylonitrile Acrylonitrile — CO2, secondary products burned/flared (default) CO₂ 1 tonne CO₂ per tonne acrylonitrile
Adipic acid Adipic acid — net EF after catalytic destruction abatement N₂O 53 kg N₂O per tonne adipic acid
Adipic acid Adipic acid — net EF after recycle-to-feedstock abatement N₂O 49 kg N₂O per tonne adipic acid
Adipic acid Adipic acid — net EF after recycle-to-nitric-acid abatement N₂O 22.2 kg N₂O per tonne adipic acid
Adipic acid Adipic acid — net EF after thermal destruction abatement N₂O 13.4 kg N₂O per tonne adipic acid
Adipic acid Adipic acid — nitric acid oxidation, uncontrolled (no abatement) N₂O 300 kg N₂O per tonne adipic acid
Ammonia Ammonia — average value, partial oxidation CO₂ 3.273 tonne CO₂ per tonne NH₃
Ammonia Ammonia — European average value, natural gas (mix of modern and older plants) CO₂ 2.104 tonne CO₂ per tonne NH₃
Ammonia Ammonia — modern autothermal reforming, natural gas CO₂ 1.694 tonne CO₂ per tonne NH₃
Ammonia Ammonia — modern conventional reforming, natural gas CO₂ 1.694 tonne CO₂ per tonne NH₃
Ammonia Ammonia — modern excess air reforming, natural gas CO₂ 1.666 tonne CO₂ per tonne NH₃
Ammonia Ammonia — modern partial oxidation CO₂ 2.772 tonne CO₂ per tonne NH₃
Caprolactam Caprolactam — Raschig process N₂O 9 kg N₂O per tonne caprolactam
Carbide Calcium carbide production — CO2 from petroleum coke use CO₂ 1.09 tonne CO₂ per tonne calcium carbide produced
Carbide Calcium carbide use — CO2 from acetylene production downstream CO₂ 1.1 tonne CO₂ per tonne calcium carbide used
Carbide Silicon carbide production — CH4 CH₂ 11.6 kg CH₂ per tonne silicon carbide produced
Carbide Silicon carbide production — CO2 CO₂ 2.62 tonne CO₂ per tonne silicon carbide produced
Carbon black Carbon black — CH4, no thermal treatment CH₂ 28.7 kg CH₂ per tonne carbon black
Carbon black Carbon black — CH4, thermal treatment (default) CH₂ 0.06 kg CH₂ per tonne carbon black
Carbon black Carbon black — CO2 from Acetylene Black process (total) CO₂ 0.78 tonne CO₂ per tonne carbon black
Carbon black Carbon black — CO2 from Furnace Black process (default, total) CO₂ 2.62 tonne CO₂ per tonne carbon black
Carbon black Carbon black — CO2 from Thermal Black process (total) CO₂ 5.25 tonne CO₂ per tonne carbon black
Carbon content Acetonitrile — carbon content CO₂ 0.5852 tonne carbon per tonne acetonitrile
Carbon content Acrylonitrile — carbon content CO₂ 0.6664 tonne carbon per tonne acrylonitrile
Carbon content Butadiene — carbon content CO₂ 0.888 tonne carbon per tonne butadiene
Carbon content Carbon black feedstock — carbon content CO₂ 0.9 tonne carbon per tonne carbon black feedstock
Carbon content Carbon black — carbon content CO₂ 0.97 tonne carbon per tonne carbon black
Carbon content Ethane — carbon content CO₂ 0.856 tonne carbon per tonne ethane
Carbon content Ethylene dichloride — carbon content CO₂ 0.245 tonne carbon per tonne ethylene dichloride
Carbon content Ethylene glycol — carbon content CO₂ 0.387 tonne carbon per tonne ethylene glycol
Carbon content Ethylene oxide — carbon content CO₂ 0.545 tonne carbon per tonne ethylene oxide
Carbon content Ethylene — carbon content CO₂ 0.856 tonne carbon per tonne ethylene
Carbon content Hydrogen cyanide — carbon content CO₂ 0.4444 tonne carbon per tonne hydrogen cyanide
Carbon content Methane — carbon content CO₂ 0.749 tonne carbon per tonne methane
Carbon content Methanol — carbon content CO₂ 0.375 tonne carbon per tonne methanol
Carbon content Propane — carbon content CO₂ 0.817 tonne carbon per tonne propane
Carbon content Propylene — carbon content CO₂ 0.8563 tonne carbon per tonne propylene
Carbon content Vinyl chloride monomer — carbon content CO₂ 0.384 tonne carbon per tonne VCM
Edc / vcm EDC/VCM — CH4 from integrated production plant CH₂ 0.0226 kg CH₂ per tonne VCM produced
Edc / vcm EDC/VCM — CO2 from Balanced Process (default, VCM basis) CO₂ 0.294 tonne CO₂ per tonne VCM produced
Edc / vcm EDC/VCM — CO2 from Direct Chlorination process (VCM basis) CO₂ 0.286 tonne CO₂ per tonne VCM produced
Edc / vcm EDC/VCM — CO2 from Oxychlorination process (VCM basis) CO₂ 0.302 tonne CO₂ per tonne VCM produced
Edc / vcm EDC/VCM — ethylene feedstock consumption, Balanced Process (VCM basis) CO₂ 0.47 tonne ethylene per tonne VCM produced
Ethylene Ethylene — CH4 from steam cracking, all other feedstocks CH₂ 3 kg CH₂ per tonne ethylene
Ethylene Ethylene — CH4 from steam cracking, ethane feedstock CH₂ 6 kg CH₂ per tonne ethylene
Ethylene Ethylene — CH4 from steam cracking, naphtha feedstock CH₂ 3 kg CH₂ per tonne ethylene
Ethylene Ethylene — CO2 from steam cracking, butane feedstock CO₂ 1.07 tonne CO₂ per tonne ethylene
Ethylene Ethylene — CO2 from steam cracking, ethane feedstock CO₂ 0.95 tonne CO₂ per tonne ethylene
Ethylene Ethylene — CO2 from steam cracking, gas oil feedstock CO₂ 2.29 tonne CO₂ per tonne ethylene
Ethylene Ethylene — CO2 from steam cracking, naphtha feedstock CO₂ 1.73 tonne CO₂ per tonne ethylene
Ethylene Ethylene — CO2 from steam cracking, propane feedstock CO₂ 1.04 tonne CO₂ per tonne ethylene
Ethylene oxide Ethylene oxide — CH4, no thermal treatment (default) CH₂ 1.79 kg CH₂ per tonne ethylene oxide
Ethylene oxide Ethylene oxide — CH4, thermal treatment of process vents CH₂ 0.79 kg CH₂ per tonne ethylene oxide
Ethylene oxide Ethylene oxide — CO2 from Air Process (default catalyst selectivity 70%) CO₂ 0.863 tonne CO₂ per tonne ethylene oxide
Ethylene oxide Ethylene oxide — CO2 from Oxygen Process (default catalyst selectivity 75%) CO₂ 0.663 tonne CO₂ per tonne ethylene oxide
Fluorochemical HFC-23 byproduct from HCFC-22 production — global average 1978-1995 HFC-23 0.02 kg HFC-23 per kg HCFC-22 produced
Fluorochemical HFC-23 byproduct from HCFC-22 production — old, unoptimised plants HFC-23 0.04 kg HFC-23 per kg HCFC-22 produced
Fluorochemical HFC-23 byproduct from HCFC-22 production — recent design, not optimised HFC-23 0.03 kg HFC-23 per kg HCFC-22 produced
Glyoxal Glyoxal production — Tier 1 net EF (post-destruction) N₂O 0.1 tonne N₂O per tonne glyoxal
Glyoxylic acid Glyoxylic acid production — Tier 1 net EF (post-destruction) N₂O 0.02 tonne N₂O per tonne glyoxylic acid
Methanol Methanol production — CH4 (Tier 1 default) CH₂ 2.3 kg CH₂ per tonne methanol
Methanol Methanol — conventional steam reforming with primary reformer, natural gas CO₂ 0.497 tonne CO₂ per tonne methanol
Methanol Methanol — conventional steam reforming, no primary reformer, natural gas (default) CO₂ 0.67 tonne CO₂ per tonne methanol
Methanol Methanol — integrated with ammonia production, natural gas CO₂ 1.02 tonne CO₂ per tonne methanol
Methanol Methanol — Lurgi Combined Steam Reforming process, natural gas CO₂ 0.396 tonne CO₂ per tonne methanol
Methanol Methanol — Lurgi Conventional process, natural gas CO₂ 0.385 tonne CO₂ per tonne methanol
Methanol Methanol — Lurgi Low Pressure process, natural gas CO₂ 0.267 tonne CO₂ per tonne methanol
Methanol Methanol — Lurgi Mega Methanol process, natural gas CO₂ 0.31 tonne CO₂ per tonne methanol
Nitric acid Nitric acid — atmospheric (low) pressure plants N₂O 5 kg N₂O per tonne nitric acid (100% pure)
Nitric acid Nitric acid — high pressure plants N₂O 9 kg N₂O per tonne nitric acid (100% pure)
Nitric acid Nitric acid — medium pressure combustion plants N₂O 7 kg N₂O per tonne nitric acid (100% pure)
Nitric acid Nitric acid — plants with NSCR abatement N₂O 2 kg N₂O per tonne nitric acid (100% pure)
Nitric acid Nitric acid — plants with process-integrated or tailgas N2O destruction N₂O 2.5 kg N₂O per tonne nitric acid (100% pure)
Soda ash Natural soda ash — CO2 per tonne natural soda ash produced (output basis) CO₂ 0.138 tonne CO₂ per tonne natural soda ash produced
Soda ash Natural soda ash — CO2 per tonne Trona consumed (input basis) CO₂ 0.097 tonne CO₂ per tonne Trona
Tio2 Titanium dioxide — rutile via chloride route CO₂ 1.34 tonne CO₂ per tonne rutile TiO2 produced
Tio2 Titanium dioxide — synthetic rutile production CO₂ 1.43 tonne CO₂ per tonne synthetic rutile produced

Metal industry — 46 rows

Iron and steel, ferroalloys, aluminium, magnesium, lead and zinc.

Metal industry — IPCC industrial-process emission factors
Category Process / parameter Gas Value Unit
Aluminium Primary aluminium PFC — C2F6 (CWPB) C₂F₆ 0.04 kg C₂F₆ per tonne Al
Aluminium Primary aluminium PFC — C2F6 (HSS) C₂F₆ 0.03 kg C₂F₆ per tonne Al
Aluminium Primary aluminium PFC — C2F6 (SWPB) C₂F₆ 0.4 kg C₂F₆ per tonne Al
Aluminium Primary aluminium PFC — C2F6 (VSS) C₂F₆ 0.04 kg C₂F₆ per tonne Al
Aluminium Primary aluminium PFC — CF4 (CWPB) CF₄ 0.4 kg CF₄ per tonne Al
Aluminium Primary aluminium PFC — CF4 (HSS) CF₄ 0.4 kg CF₄ per tonne Al
Aluminium Primary aluminium PFC — CF4 (SWPB) CF₄ 1.6 kg CF₄ per tonne Al
Aluminium Primary aluminium PFC — CF4 (VSS) CF₄ 0.8 kg CF₄ per tonne Al
Aluminium Primary aluminium — CO2 (Prebake cells) CO₂ 1.6 tonne CO₂ per tonne Al
Aluminium Primary aluminium — CO2 (Søderberg cells) CO₂ 1.7 tonne CO₂ per tonne Al
Ferroalloys Ferrochromium — CO2 (with sinter plant) CO₂ 1.6 tonne CO₂ per tonne product
Ferroalloys Ferrochromium — CO2 (without sinter plant) CO₂ 1.3 tonne CO₂ per tonne product
Ferroalloys Ferromanganese (1% C) — CO2 CO₂ 1.5 tonne CO₂ per tonne product
Ferroalloys Ferromanganese (7% C) — CO2 CO₂ 1.3 tonne CO₂ per tonne product
Ferroalloys Ferrosilicon 45% Si — CO2 CO₂ 2.5 tonne CO₂ per tonne product
Ferroalloys Ferrosilicon 65% Si — CH4 CH₂ 1 kg CH₂ per tonne product
Ferroalloys Ferrosilicon 65% Si — CO2 CO₂ 3.6 tonne CO₂ per tonne product
Ferroalloys Ferrosilicon 75% Si — CH4 CH₂ 1 kg CH₂ per tonne product
Ferroalloys Ferrosilicon 75% Si — CO2 CO₂ 4 tonne CO₂ per tonne product
Ferroalloys Ferrosilicon 90% Si — CH4 CH₂ 1.1 kg CH₂ per tonne product
Ferroalloys Ferrosilicon 90% Si — CO2 CO₂ 4.8 tonne CO₂ per tonne product
Ferroalloys Silicomanganese — CO2 CO₂ 1.4 tonne CO₂ per tonne product
Ferroalloys Silicon metal — CH4 CH₂ 1.2 kg CH₂ per tonne product
Ferroalloys Silicon metal — CO2 CO₂ 5 tonne CO₂ per tonne product
Iron steel Basic oxygen furnace steel — CO2 CO₂ 1.46 tonne CO₂ per tonne steel
Iron steel Blast furnace iron production — CO2 CO₂ 1.35 tonne CO₂ per tonne pig iron
Iron steel Coke oven production — CO2 CO₂ 0.56 tonne CO₂ per tonne coke
Iron steel Coke production — CH4 CH₂ 0.1 g CH₂ per tonne coke
Iron steel Direct reduced iron production — CH4 CH₂ 1 kg CH₂ per TJ
Iron steel Direct reduced iron production — CO2 CO₂ 0.7 tonne CO₂ per tonne DRI
Iron steel Electric arc furnace steel — CO2 CO₂ 0.08 tonne CO₂ per tonne steel
Iron steel Global average steel (65% BOF / 30% EAF / 5% OHF) — CO2 CO₂ 1.06 tonne CO₂ per tonne steel
Iron steel Iron ore pellet production — CO2 CO₂ 0.03 tonne CO₂ per tonne pellet
Iron steel Open hearth furnace steel — CO2 CO₂ 1.72 tonne CO₂ per tonne steel
Iron steel Sinter production — CH4 CH₂ 0.07 kg CH₂ per tonne sinter
Iron steel Sinter production — CO2 CO₂ 0.2 tonne CO₂ per tonne sinter
Lead Lead production — CO2 (direct smelting) CO₂ 0.25 tonne CO₂ per tonne Pb
Lead Lead production — CO2 (Imperial Smelting Furnace) CO₂ 0.59 tonne CO₂ per tonne Pb
Lead Lead production — CO2 (secondary / recycled) CO₂ 0.2 tonne CO₂ per tonne Pb
Lead Lead production — CO2 (weighted default) CO₂ 0.52 tonne CO₂ per tonne Pb
Magnesium Magnesium casting — SF6 cover gas SF₆ 1 kg SF₆ per tonne Mg cast
Magnesium Primary magnesium — CO2 (from dolomite) CO₂ 5.13 tonne CO₂ per tonne Mg
Magnesium Primary magnesium — CO2 (from magnesite) CO₂ 2.83 tonne CO₂ per tonne Mg
Zinc Zinc production — CO2 (Imperial Smelting Furnace) CO₂ 0.43 tonne CO₂ per tonne Zn
Zinc Zinc production — CO2 (Waelz Kiln) CO₂ 3.66 tonne CO₂ per tonne Zn
Zinc Zinc production — CO2 (weighted default) CO₂ 1.72 tonne CO₂ per tonne Zn

Non-energy products from fuels — 8 rows

Lubricants and paraffin wax oxidised in use rather than burned as fuel.

Non-energy products from fuels — IPCC industrial-process emission factors
Category Process / parameter Gas Value Unit
Lubricants Lubricants — default mass fraction of grease in total lubricants CO₂ 0.1 dimensionless mass fraction
Lubricants Lubricants — default mass fraction of lubricating oil in total lubricants CO₂ 0.9 dimensionless mass fraction
Lubricants Lubricants — IPCC default ODU factor for total lubricants CO₂ 0.2 dimensionless ODU fraction
Lubricants Lubricants — ODU factor for grease CO₂ 0.05 dimensionless ODU fraction
Lubricants Lubricants — ODU factor for lubricating oil (motor / industrial) CO₂ 0.2 dimensionless ODU fraction
Paraffin wax Paraffin wax — default carbon content CO₂ 20 kg C per GJ (Lower Heating Value basis)
Paraffin wax Paraffin wax — default combustion emission factor (full oxidation) CO₂ 73.3 kg CO₂ per GJ (NCV basis)
Paraffin wax Paraffin wax — IPCC default ODU factor CO₂ 0.2 dimensionless ODU fraction

2019 Refinement additions — 54 rows

Categories added or revised by the 2019 Refinement — aluminium PFCs, hydrogen production, rare earths, and updated nitric-acid and fluorochemical factors.

2019 Refinement additions — IPCC industrial-process emission factors
Category Process / parameter Gas Value Unit
Aluminium pfc Aluminium PFC — HSS HVAE-C2F6 Tier 1 EF, 2019 Refinement C₂F₆ 0.033 kg C₂F₆ per tonne aluminium
Aluminium pfc Aluminium PFC — HSS HVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.477 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — HSS LVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.026 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — PFPBL HVAE-C2F6 Tier 1 EF, 2019 Refinement C₂F₆ 0.001 kg C₂F₆ per tonne aluminium
Aluminium pfc Aluminium PFC — PFPBL HVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.016 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — PFPBL LVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.009 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — PFPBM HVAE-C2F6 Tier 1 EF, 2019 Refinement C₂F₆ 0.001 kg C₂F₆ per tonne aluminium
Aluminium pfc Aluminium PFC — PFPBM HVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.011 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — PFPBM LVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.018 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — PFPBMW HVAE-C2F6 Tier 1 EF, 2019 Refinement C₂F₆ 0.013 kg C₂F₆ per tonne aluminium
Aluminium pfc Aluminium PFC — PFPBMW HVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.161 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — SWPB HVAE-C2F6 Tier 1 EF, 2019 Refinement C₂F₆ 0.093 kg C₂F₆ per tonne aluminium
Aluminium pfc Aluminium PFC — SWPB HVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.354 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — SWPB LVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.01 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — VSS HVAE-C2F6 Tier 1 EF, 2019 Refinement C₂F₆ 0.009 kg C₂F₆ per tonne aluminium
Aluminium pfc Aluminium PFC — VSS HVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.159 kg CF₄ per tonne aluminium
Aluminium pfc Aluminium PFC — VSS LVAE-CF4 Tier 1 EF, 2019 Refinement CF₄ 0.001 kg CF₄ per tonne aluminium
Fluorochemical All other fluorochemicals — Tier 1 default EF (total mass), 2019 Refinement mixed F-gases 0.04 kg fluorinated GHG per kg fluorochemical produced
Fluorochemical NF3 production EF — CF4 by-product (Tier 1), 2019 Refinement CF₄ 0.01 kg CF₄ per kg NF₃ produced
Fluorochemical NF3 production EF — N2O by-product (Tier 1), 2019 Refinement N₂O 0.03 kg N₂O per kg NF₃ produced
Fluorochemical NF3 production EF — NF3 emission (Tier 1), 2019 Refinement NF₃ 0.02 kg NF₃ per kg NF₃ produced
Fluorochemical SF6 production EF — Tier 1 alternative (Suizu 1999), 2019 Refinement SF₆ 0.08 kg SF₆ per kg SF₆ produced
Fluorochemical SF6 production EF — Tier 1 default (O’Connell 2002), 2019 Refinement SF₆ 0.03 kg SF₆ per kg SF₆ produced
Hfc-23 / hcfc-22 HFC-23 emission from HCFC-22 production — global average 1978-1995, 2019 Refinement HFC-23 0.02 kg HFC-23 per kg HCFC-22 produced
Hfc-23 / hcfc-22 HFC-23 emission from HCFC-22 production — old unoptimised plants, 2019 Refinement HFC-23 0.04 kg HFC-23 per kg HCFC-22 produced
Hfc-23 / hcfc-22 HFC-23 emission from HCFC-22 production — recent design plants (not specifically optimised), 2019 Refinement HFC-23 0.03 kg HFC-23 per kg HCFC-22 produced
Hydrogen Hydrogen — biosteam reforming of bioethanol (Tier 1 CCF), 2019 Refinement CO₂ 0.0217 tonne C per GJ feedstock
Hydrogen Hydrogen — gasification of black liquor (Tier 1 CCF), 2019 Refinement CO₂ 0.026 tonne C per GJ feedstock
Hydrogen Hydrogen — gasification of coking coal (Tier 1 CCF), 2019 Refinement CO₂ 0.0258 tonne C per GJ feedstock
Hydrogen Hydrogen — gasification of mixed plastic (Tier 1 CCF), 2019 Refinement CO₂ 0.02 tonne C per GJ feedstock
Hydrogen Hydrogen — gasification of mixed waste (non-biomass fraction) (Tier 1 CCF), 2019 Refinement CO₂ 0.025 tonne C per GJ feedstock
Hydrogen Hydrogen — gasification of wood sludge (Tier 1 CCF), 2019 Refinement CO₂ 0.0305 tonne C per GJ feedstock
Hydrogen Hydrogen — gasification of wood waste (Tier 1 CCF), 2019 Refinement CO₂ 0.0305 tonne C per GJ feedstock
Hydrogen Hydrogen — general default (mixed-feedstock global average) (Tier 1 CCF), 2019 Refinement CO₂ 0.0183 tonne C per GJ feedstock
Hydrogen Hydrogen — steam reforming of LPG (Tier 1 CCF), 2019 Refinement CO₂ 0.0172 tonne C per GJ feedstock
Hydrogen Hydrogen — steam reforming of methanol (Tier 1 CCF), 2019 Refinement CO₂ 0.0188 tonne C per GJ feedstock
Hydrogen Hydrogen — steam reforming of naphtha (Tier 1 CCF), 2019 Refinement CO₂ 0.02 tonne C per GJ feedstock
Hydrogen Hydrogen — steam reforming of natural gas (Tier 1 CCF), 2019 Refinement CO₂ 0.0153 tonne C per GJ feedstock
Nitric acid Nitric acid — dual L/M pressure with N2O abatement, 2019 Refinement N₂O 1.5 kg N₂O per tonne 100% nitric acid
Nitric acid Nitric acid — dual low/medium pressure (L/M), 2019 Refinement N₂O 7 kg N₂O per tonne 100% nitric acid
Nitric acid Nitric acid — dual M/H pressure with N2O abatement, 2019 Refinement N₂O 2.5 kg N₂O per tonne 100% nitric acid
Nitric acid Nitric acid — dual medium/high pressure (M/H), 2019 Refinement N₂O 9 kg N₂O per tonne 100% nitric acid
Nitric acid Nitric acid — old (pre-1975) plants (all processes), 2019 Refinement N₂O 14.5 kg N₂O per tonne 100% nitric acid
Nitric acid Nitric acid — single high pressure plants (H/H), 2019 Refinement N₂O 9 kg N₂O per tonne 100% nitric acid
Nitric acid Nitric acid — single low pressure plants (L/L), 2019 Refinement N₂O 5 kg N₂O per tonne 100% nitric acid
Nitric acid Nitric acid — single medium pressure plants (M/M), 2019 Refinement N₂O 8 kg N₂O per tonne 100% nitric acid
Nitric acid Nitric acid — single pressure plants with N2O abatement, 2019 Refinement N₂O 2.5 kg N₂O per tonne 100% nitric acid
Rare earths Rare earth metal production — CO2 from anode consumption (Tier 1), 2019 Refinement (NEW) CO₂ 0.56 tonne CO₂ per tonne RE metal
Rare earths Rare earth — Other rare earth metals/alloys C2F6 Tier 1 EF, 2019 Refinement (NEW) C₂F₆ 5.2 g C₂F₆ per tonne RE metal
Rare earths Rare earth — Other rare earth metals/alloys C3F8 Tier 1 EF, 2019 Refinement (NEW) C₃F₈ 0.21 g C₃F₈ per tonne RE metal
Rare earths Rare earth — Other rare earth metals/alloys CF4 Tier 1 EF, 2019 Refinement (NEW) CF₄ 35.8 g CF₄ per tonne RE metal
Rare earths Rare earth — Rare-earth-iron C2F6 Tier 1 EF, 2019 Refinement (NEW) C₂F₆ 14.6 g C₂F₆ per tonne RE metal
Rare earths Rare earth — Rare-earth-iron C3F8 Tier 1 EF, 2019 Refinement (NEW) C₃F₈ 0.05 g C₃F₈ per tonne RE metal
Rare earths Rare earth — Rare-earth-iron CF4 Tier 1 EF, 2019 Refinement (NEW) CF₄ 146.1 g CF₄ per tonne RE metal

Application — worked examples

Process emissions are an activity rate multiplied by a factor, then converted to CO₂e using your own GWP set. Both examples use values exactly as published in the tables.

Cement — clinker-based (IPCC Tier 2)

A plant produces 100,000 tonnes of ordinary Portland cement. The factor applies to clinker, not to cement, so the clinker fraction comes first.

clinker = 100,000 t cement x 0.95 t clinker/t cement = 95,000 t clinker
CO2     = 95,000 t clinker x 0.52 t CO2/t clinker    = 49,400 t CO2

The 0.52 factor already carries the cement-kiln-dust correction: the pre-CKD value is 0.51 and the default CKD multiplier is 1.02, and 0.51 × 1.02 = 0.52. Applying the CKD correction a second time on top of 0.52 double-counts it — a common error when the two rows are read as independent inputs rather than as a factor and its derivation.

This figure is the calcination term only. The fuel burned to fire the kiln is stationary combustion and is reported separately.

Nitric acid — why the per-gas basis matters

A plant produces 50,000 tonnes of 100% nitric acid in a high-pressure process with no abatement. The factor is 9 kg N₂O per tonne.

N2O   = 50,000 t x 9 kg/t = 450,000 kg = 450 t N2O
CO2e  = 450 t N2O x 273 (IPCC AR6, 100-year) = 122,850 t CO2e

Four hundred and fifty tonnes of gas becomes roughly 123,000 tonnes of CO₂e. Reporting the 450 without applying the GWP would understate this single category by more than a hundredfold, and it is the reason this dataset keeps the gas explicit rather than pre-converting.

Abatement changes the picture sharply. The same plant fitted with non-selective catalytic reduction uses a factor of 2 kg N₂O per tonne, giving 100 t N₂O and about 27,300 t CO₂e — a 78% reduction from equipment alone, with no change in output.

Calculators that use these factors

The worked examples above are automated in these GreenCalculus tools, which read this dataset live from the MasterBrain so results always reflect the current vintage:

Common reporting errors

  • Treating a per-gas figure as CO₂e. The dominant error in this sector. Every non-CO₂ row on this page needs a GWP applied before it can join a CO₂e total.
  • Reporting only fuel combustion. For cement, lime, ammonia and hydrogen the process term is comparable to or larger than the combustion term. An inventory with only fuel is not conservative, it is incomplete.
  • Applying a clinker factor to cement tonnage. The mineral factors are per tonne of clinker; cement is clinker plus supplementary materials. Skipping the clinker fraction overstates the emission by roughly 5% for Portland cement and far more for blended and masonry cements.
  • Double-counting the CKD correction. The published 0.52 already includes it. Use either the corrected default or the pre-CKD value with the multiplier, never both.
  • Mixing IPCC editions without saying which. Nitric acid and the fluorochemicals appear in both the 2006 guidelines and the 2019 Refinement with different values. Pick the edition your reporting framework requires and record it.
  • Ignoring abatement. Nitric-acid and adipic-acid factors vary several-fold with installed abatement technology. Using an unabated default for an abated plant is as wrong as the reverse.

Methodology, tiers & uncertainty

Tier structure. IPCC methods run from Tier 1 (a default factor applied to national or site production) through Tier 2 (default factors refined by process-specific parameters such as clinker fraction or carbonate composition) to Tier 3 (plant-specific measurement or full mass balance). The factors here support Tier 1 and Tier 2. A facility with continuous emissions monitoring or a verified carbon mass balance should use that instead — a measured value always supersedes a default.

Defaults are global, not local. These are international defaults intended for national inventory compilation. Real plants vary widely around them with raw-material composition, process route, vintage and installed abatement. They are appropriate where plant-specific data is genuinely unavailable, and should be replaced as soon as it is not.

GWP basis is yours to choose. No GWP set is baked into any value here. Apply AR6 100-year for current GHG Protocol and CSRD reporting, or AR5 where a framework still requires it, and state which you used — the difference is material for N₂O and the fluorinated gases.

Uncertainty. IPCC assigns wide uncertainty ranges to Tier 1 process defaults, frequently ±10–30% and considerably more for the fluorinated-gas categories where emissions depend on operating practice rather than stoichiometry. Carbonate stoichiometry is the exception: those values are fixed by chemistry and carry essentially no uncertainty for pure material.

Implementation & provenance chain

Every row traces to its IPCC volume and edition. Nothing is hand-transcribed: the tables are generated from the same MasterBrain rows the REST endpoint serves, and the generator asserts that all 224 source keys render exactly once before the page is built.

Provenance chain
Stage What it is
Primary sources IPCC 2006 Guidelines for National Greenhouse Gas Inventories, Volume 3 (IPPU); and the 2019 Refinement to the 2006 Guidelines
Edition marker Each row carries source_id of either IPCC_2006_VOL3 or IPCC_2019_REFINEMENT in the API response
Data layer GreenCalculus MasterBrain — canonical keyspace under the industrial_processes section, version-stamped
Gas basis Per gas as published; no GWP applied at any stage of the chain
Licence IPCC Guidelines are published for public use in national inventory compilation

Data access — REST API & CSV

The full 224-row dataset is available as a machine-readable REST endpoint and as a flat CSV download. Both serve exactly the rows shown in the tables above, versioned by MasterBrain edition and citable.

JSON — REST API
All 224 IPPU parameters with keys, values, gas, process-specific units and IPCC edition markers. Cache-Control: max-age=3600; X-GC-Version header signals dataset updates.

/wp-json/greencalculus/v1/ippu-factors

Open API endpoint →

CSV — flat dataset
Flat CSV of all 224 rows (key, name, value, unit, gas, GWP set, GHG scope/category, source, note) — ready for spreadsheet import.

Click to generate ↓

Citation guidance

If you use this dataset in a published tool, report or academic work, cite the IPCC primary sources. The GreenCalculus compilation reference is optional but appreciated.

IPCC (2006). 2006 IPCC Guidelines for National Greenhouse Gas Inventories, Volume 3: Industrial Processes and Product Use. Prepared by the National Greenhouse Gas Inventories Programme, Eggleston H.S., Buendia L., Miwa K., Ngara T. and Tanabe K. (eds). IGES, Japan.

IPCC 2006 Guidelines primary citation

IPCC (2019). 2019 Refinement to the 2006 IPCC Guidelines for National Greenhouse Gas Inventories. Calvo Buendia E., Tanabe K., Kranjc A., Baasansuren J., Fukuda M., Ngarize S., Osako A., Pyrozhenko Y., Shermanau P. and Federici S. (eds). IPCC, Switzerland.

IPCC 2019 Refinement primary citation

Cite this dataset (GreenCalculus compilation). A versioned, machine-readable snapshot of these factors is archived on Zenodo with a citable DOI:

Say, Jeremiah (2026). IPCC industrial-process & product-use (IPPU) emission factors (machine-readable) (v2026.107). GreenCalculus. Zenodo. https://doi.org/10.5281/zenodo.21831123

GreenCalculus dataset DOI

Frequently asked questions

Combustion emissions come from burning a fuel to supply energy. Process emissions come from the chemical or physical transformation of the material itself and would occur even if the energy were entirely renewable. A cement kiln does both: it burns fuel for heat, and it drives limestone to decompose into lime and carbon dioxide. Both are Scope 1, but they take different factors, scale with different activity data, and respond to different mitigation measures.

Because the IPCC publishes them per gas, and converting them for you would bake in a global warming potential set that may not be the one your framework requires. Eight gases appear across this dataset. Applying AR6 100-year values gives a different answer from AR5, and some national inventory submissions still require the older set. Keeping the gas explicit means the conversion is yours to make and yours to document.

Scope 1, when the process happens in equipment you own or control. They are not a separate scope, but they are a separate category within Scope 1 and should be reported apart from stationary and mobile combustion. If you buy a material whose production caused process emissions rather than making it yourself, those emissions are in your Scope 3 Category 1 instead, and are quantified from the supplier’s product footprint rather than from these factors.

To clinker. Calcination happens when clinker is made, and cement is clinker blended with supplementary materials that carry no calcination emission of their own. Multiply cement tonnage by the clinker fraction first — 0.95 for ordinary Portland cement by default, 0.64 for masonry cement — then apply the clinker factor. Applying the factor directly to cement tonnage overstates Portland cement by about 5% and blended cements by far more.

Because both current IPCC editions are published here rather than merged. Nitric acid and the fluorochemicals appear in the 2006 Guidelines and again in the 2019 Refinement, which revised them. National inventories still report against whichever edition their submission requires, and a value cannot be traced if the edition it came from has been erased. The source_id field distinguishes them on every row — pick the edition your framework specifies and record the choice.

Because nitrous oxide output depends heavily on the process route and on what abatement is installed. A high-pressure nitric-acid plant with no abatement emits 9 kg N₂O per tonne; the same plant with non-selective catalytic reduction emits 2. That is a 78% difference driven purely by equipment, so using a generic default for a plant whose configuration you know will be materially wrong in one direction or the other. Match the factor to the actual process route and abatement.

They give the theoretical CO₂ released per tonne of a pure carbonate, fixed by molecular weight — 0.43971 for calcite, 0.47732 for dolomite, and so on. They are used when you know the carbonate composition of your raw material but have no process-specific factor, which is the IPCC Tier 2 route for mineral industries. Because they follow from chemistry rather than measurement they carry essentially no uncertainty for pure material, though real feedstock is never entirely pure.

Only where measured data is genuinely unavailable. These are IPCC Tier 1 and Tier 2 defaults intended for national inventory compilation, and real plants vary widely around them with raw-material composition, process vintage and installed abatement. If you hold continuous emissions monitoring data or a verified carbon mass balance, that is Tier 3 and supersedes any default here. The defaults are a floor for completeness, not a substitute for measurement.

Version history

Substantive revisions to this dataset reference page
Version Date MasterBrain Summary
1.0 2026-08-06 v2026.105 Initial publication. Complete IPPU dataset (224 parameters, 8 gases) from IPCC 2006 Vol.3 and the 2019 Refinement: mineral, chemical and metal industries, non-energy products, carbonate stoichiometry. Process-versus-combustion explainer, per-gas GWP guidance, edition split, worked examples, 8-item FAQ, REST + CSV access.

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